/usr/share/glib-2.0/schemas/org.gnome.system.smb.gschema.xml is in gvfs-common 1.12.1-0ubuntu1.
This file is owned by root:root, with mode 0o644.
The actual contents of the file can be viewed below.
1 2 3 4 5 6 7 8 9 | <schemalist>
<schema id="org.gnome.system.smb" path="/system/smb/">
<key name="workgroup" type="s">
<default>''</default>
<summary>SMB workgroup</summary>
<description>The Windows networking workgroup or domain that the user is part of. In order for a new workgroup to fully take effect the user may need to log out and log back in.</description>
</key>
</schema>
</schemalist>
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